海水化学演化对生物矿化的影响综述   总被引：1，自引：1，他引：0       下载免费PDF全文

刘喜停  颜佳新 《古地理学报》2009,11(4):446

显生宙非骨屑碳酸盐矿物经历了文石海和方解石海的交替,主要造礁生物和沉积物生产者的骨骼矿物与非骨屑碳酸盐矿物具有同步变化的趋势。这种长期的变化趋势可以用海水化学Mg/Ca摩尔比的变化来解释。流体包裹体、同位素和微量元素等证据也证实了海水化学在地质历史中经历过剧烈的变化。虽然生物诱导矿化和生物控制矿化的相对重要性一直存在争议,但古生物地层记录和人工海水养殖实验结果都表明,海水化学演化对生物矿化有重要的影响,体现在造礁生物群落的兴衰、生物起源时对骨骼矿物类型的选择以及微生物碳酸盐岩在地质历史中的分布等。这些为研究前寒武纪海水化学演化、古气候和古环境的重建、同位素地层对比以及碳酸盐的沉积和成岩等问题提供了新的思路。  相似文献   

离线固相萃取螯合富集分离-ICP-MS测定海水中的稀土元素   总被引：1，自引：0，他引：1  

刘瑶  宋金明  林强  于颖  孙玲玲  温廷宇 《海洋科学》2017,41(9):34-40

通过测定条件优化、方法比对等实验建立了一种固相萃取小柱离线螯合富集分离电感耦合等离子体质谱仪测定海水中稀土元素的方法。海水样品通过调节p H后,进入VAC ELUT SPS24 Agilent圆形固相萃取装置,其主要基体物质的去除率高于97%;萃取富集的优化条件是海水样品p H 4.0~7.0,海水进入萃取柱速率2 m L/min,硝酸洗脱液浓度为1 mol/L;方法对稀土元素的加标回收率为83%~108%,14种稀土元素的检出限为0.057~0.613 ng/L,RSD10%;该方法与氢氧化铁共沉淀法富集稀土元素比对测定结果一致,方法具有准确度与精密度高、操作简便快速等优点,可用于海水样品中稀土元素的定量精确测量。  相似文献   

NOBIAS PA1螯合树脂富集——ICP-MS定量测定近海水体中的稀土元素   总被引：1，自引：0，他引：1  

梁杰  何会军  麻洪良  杨士凤  张劲 《海洋科学》2017,41(10):58-66

稀土元素是海洋中一类极为重要的地球化学过程的示踪剂,但因其浓度多在pmol/kg数量级,分析测试一直是难点,为了使稀土元素在海洋研究中得到更广泛的应用,必须对海洋中低浓度的稀土元素进行准确测量。本研究建立了NOBIAS PA1螯合树脂富集—ICP-MS法,可以对近海的小体积水样中的稀土元素进行高准确度、高精密度分析。研究表明,调节样品溶液pH为4.59~4.69、清洗溶液为6 mL 0.05 mol/L NH_4AC、洗脱溶液为2 mL 1 mol/L HNO_3时,实验测试条件为最优。本方法对稀土元素的回收率在94%~106%,检出限范围为0.001~0.424 pmol/kg,分析精密度优于5%(n=5)。本研究所建立的方法,可用于河水、海水与河口盐度梯度区稀土元素的分析。  相似文献   

Toxic cyanobacteria at Nakuru sewage oxidation ponds - A potential threat to wildlife     

Kiplagat Kotut  Claudia Wiegand 《Limnologica》2010,40(1):47-53

Phytoplankton composition and biomass, and microcystin content were determined on diverse dates between November 2001 and June 2006 in the final oxidation pond of the Nakuru town sewage treatment plant. The oxidation ponds as well as the rivulet that drains the same are important water sources for some wildlife in the park. The phytoplankton composition of the pond studied mostly comprised coccoid green alga species. However, occasionally cyanobacteria or euglenoids were dominant. Among the cyanobacteria, Microcystis sp. made periodic appearance in the phytoplankton, and was the dominant species on some occasions. Total phytoplankton biomass varied widely from 48 to 135 mg L⁻¹ (wet weight) while cyanobacteria biomass ranged from undetectable levels to 130 mg L⁻¹. Most phytoplankton biomass was due to one or a few species. Detectable cyanotoxin concentrations (sum of microcystins) of up to 551.08 μg mg⁻¹ dry weight (DW) of cyanobacteria biomass or 0.28 μg mg⁻¹ DW of total phytoplankton biomass were recorded in samples collected on different dates. Microcystin content did not appear to correspond to the biomass of cyanobacteria suggesting that toxin production is possibly triggered by environmental changes or changes in the proportion of toxic strains. An occasional presence of microcystins in the pond water suggests that the wildlife species, which regularly use the ponds as drinking water sources are potentially exposed to intoxication. A close monitoring of pond water phytoplankton composition is necessary to accurately quantify the potential impact of cyanotoxins on these wildlife species.  相似文献   

Liquefaction behaviour of loose and compacted pond ash     

Ravi S. Jakka  Manoj Datta  G.V. Ramana 《Soil Dynamics and Earthquake Engineering》2010

Most of the ash produced all over the world is primarily disposed off by wet disposal method onto the ash ponds, which are occupying huge valuable lands. This disposal problem can be minimized by utilizing ash in large geotechnical earthworks. However, its use in earthquake prone areas requires thorough understanding of its liquefaction resistance and nature of development of excess pore pressures under dynamic loading conditions. Investigations have been carried out in this paper on the liquefaction behaviour of pond ash by conducting cyclic triaxial tests on inflow and outflow ash samples collected from two different ash ponds. Distinctly different liquefaction phenomenon was observed for the ash samples from inflow and outflow points of the same ash pond. Inflow samples exhibited higher cyclic resistance than outflow samples and their strengths were comparable with the natural sands. Further studies revealed that the influence of various factors on liquefaction susceptibility of both the types of ashes is similar to that of natural sands.  相似文献   

汕尾电厂临时倾倒区对所在海域及其周边环境的影响     

李壮伟 《广东海洋大学学报》2010,30(6)

分析汕尾电厂临时倾倒区2006年倾倒的疏浚泥对所在海域水质、沉积物、生物群落及生物质量等的影响。结果表明,在倾倒过程中,海水中悬浮物、石油类的含量增加,属第三类海水水质;倾倒活动改变了生物群落的水环境,使群落种数减少,多样性、均匀度和丰度降低。倾倒活动结束1个月后,除海水中悬浮物的含量仍属第三类海水水质外,其他污染物含量均符合第二类海水水质标准,底栖生物恢复较缓慢。疏浚泥倾倒对海区沉积物质量和海洋生物质量的影响较小。  相似文献   

群岛峡道浓盐水排放扩散的三维数值模拟          下载免费PDF全文

李春辉  李瑞杰  肖千璐  傅小燕  张海春 《海洋学研究》2016,34(4):39-45

采用三维潮流温盐数学模型对六横岛附近海域的水动力环境及盐度场分布进行数值模拟,并以实测资料进行验证,所建立模型可以较好地反映该海域潮流动力特征及盐度场的分布情况。利用验证后的三维数学模型,对海水淡化工程浓盐水排放后盐度场分布进行计算,将排放后的盐度分布与工程前进行对比分析,并推算盐升面积及垂向盐度增量。结果表明,海水淡化工程排放的浓盐水对六横岛海域盐度分布的影响主要集中在排水口附近的底层,影响区域呈带状分布,最大盐度增量为1.2左右,且排水口附近海域出现盐度垂向分层。  相似文献   

Field Detection of Chiorophyll-a Concentration in the Sea Surface Layer by an Airborne Oceanographic Lidar   总被引：2，自引：0，他引：2  

LIU Zhishen MA Sen WANG Xin LI Zhigang 《中国海洋大学学报(英文版)》2008,7(1):108-112

An airborne oceanographic lidar, with a frequency-tripled Q-switched Nd： YAG laser of 355 nm, has been designed to measure chlorophyll-a （Chl-a） concentration in the sea surface layer by the Ocean Remote Sensing Institute, OUC. The field experiment was carried out in the bay which is located south of the Liaodong Peninsula on the 10th of September 2005. After the flight, the raw data were processed and analyzed by the fluorescence-to-Raman ratio method with seawater attenuation coefficients calculated from signal profiles. The results of Chl-a concentration sea water were also compared with those of Chl-a concentration by measurements by lidar are shown. The measurements in clear a Moderate Resolution Imaging Spectroradiometer （MODIS）.  相似文献   

Field Detection of Chlorophyll-a Concentration in the Sea Surface Layer by an Airborne Oceanographic Lidar     

LIU Zhishen  MA Sen  WANG Xin  LI Zhigang 《中国海洋大学学报(英文版)》2008,7(1)

An airborne oceanographic lidar, with a frequency-tripled Q-switched Nd: YAG laser of 355 nm, has been designed to measure chlorophyll-a (Chl-a) concentration in the sea surface layer by the Ocean Remote Sensing Institute, OUC. The field experiment was carried out in the bay which is located south of the Liaodong Peninsula on the 10th of September 2005. After the flight, the raw data were processed and analyzed by the fluorescence-to-Raman ratio method with seawater attenuation coefficients calculated from signal profiles. The results of Chl-a concentration measurements by lidar are shown. The measurements in clear sea water were also compared with those of Chl-a concentration by a Moderate Resolution Imaging Spectroradiometer (MODIS).  相似文献   

胶州湾海水中悬浮颗粒对溶解态微量元素的影响   总被引：3，自引：0，他引：3       下载免费PDF全文

刘刚  瞿成利  常凤鸣  赵永芳  路波 《海洋科学》2008,32(3):55-61

运用离子色谱离线螯合结合ICP-MS的方法,对胶州湾海水中的微量元素(V,Co,Ni,Cu,Mo,Cd,Pb,U,REEs)进行了精确的定量分析。在测试前对在同一站位不同层位采集的平行海水样品进行了两种不同的酸化处理:一份采取先过滤后酸化的方式,以获得海水中溶解态微量元素的含量;另一份采取直接酸化后分析的方式,以评估悬浮颗粒中的可交换态微量元素对溶解态微量元素测定结果可能造成的影响。通过对比研究发现,不同处理方法得到的V、Ni、Cu、Co、Pb以及稀土元素(REEs)的质量浓度存在很大差异,说明悬浮颗粒物质可能对海水中相应元素的测定产生较大的影响。各种微量元素之间的差异和相应离子或离子团的电荷性质、在海水中的配位作用以及悬浮颗粒物质的表面电荷性质有关。初步研究结果表明,在类似于胶州湾这样的近海海域,悬浮颗粒物质是控制微量元素分布特征的一个重要因素。  相似文献